Triphenylamine- and triazine-containing hydrogen bonded complexes: liquid crystalline supramolecular semiconductors

Novel Supramolecular Side-Chain Banana-Shaped Liquid Crystalline Polymers Containing Covalent- and Hydrogen-Bonded Bent Cores

Novel supramolecular side-chain banana-shaped liquid crystalline (LC) polymer complexes AmBn-N bearing various (m/n) molar ratios of hydrogenand covalent-bonded bent-core components were acquired by the free radical polymerization, where the hydrogen-bonded (H-bonded) structures were executed via mixing equimolar portions of proton donor (H-donor) polymers AmBn (homopolymers/ copolymers) and py...

Polymeric Dopant Effects of Bent-Core Covalent-Bonded and Hydrogen- Bonded Structures on Banana-Shaped Liquid Crystalline Complexes

Two series of banana-shaped liquid crystalline (LC) H-bonded complexes HPm/CBn (i.e., bent-core H-bonded sidechain homopolymer HP mixed with bent-core covalent-bonded small molecule CB) and CPm/HBn (i.e., bent-core covalent-bonded side-chain homopolymer CP mixed with bent-core H-bonded small molecular complex HB) with various m/n molar ratios were developed. The bent-core covalentand H-bonded s...

Multiple Hydrogen-Bonded Supramolecular Polymers

Fidelity in the Supramolecular Assembly of Triply and Quadruply Hydrogen-Bonded Complexes

Advancements in self-assembly and nanotechnology will require multiple assembly “codes” to be executed simultaneously. At the molecular level this will require fidelity or orthogonality in molecular recognition events. To explore the limits of orthogonal assembly, association constants (K assoc ) and dimerization constants (K dimer ) were measured with a known series of matched and mismatched r...

A novel (3,4,10)-connected three-dimensional hydrogen-bonded supramolecular network containing a cyclic water hexamer.

The title compound, 4,4'-(1,1,1,3,3,3-hexafluoroisopropylidene)diphthalic acid hexahydrate, C(19)H(10)F(6)O(8).6H(2)O, crystallizes in the centrosymmetric space group Pbcn, with half of the diphthalic acid residue and three water molecules in the asymmetric unit. The organic molecule is located on a crystallographic twofold axis. In the solid, cyclic water hexamers in chair conformations have c...